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41.
Liang-Saw Wen Peter H. Santschi Kent W. Warnken William Davison Hao Zhang Hsiu-Ping Li Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011
It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico. 相似文献
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Control and eradication of the exotic and invasive plant Spartina alterniflora within the Chongming Dongtan nature reserve, Shanghai, China, is vital for the management and conservation of the saltmarshes. A demonstration project was established using waterlogging and cutting to control this invasive species. Results from 2007 to 2008 showed that, although the managed waterlogging significantly reduced biomass and seed production of S. alterniflora at an early stage, the species subsequently showed rapid adaptation to the long-term waterlogging stress. Thus, managed waterlogging alone was insufficient for the effective eradication of S. alterniflora. However, managed waterlogging for around 3 months, combined with cutting the above-ground part of S. alterniflora at a key stage (flowering period in July), controlled and eradicated the plant successfully. Both the above-ground and below-ground parts of S. alterniflora were killed and the plants began to decompose after 3 months. Furthermore, there was no re-growth of the emergent part of S. alterniflora in the following years. However, once the impounded water was released restoring the natural hydrodynamic regime of the saltmarshes, the seeds and seedlings of S. alterniflora reinvaded the controlled site from the neighboring areas and the S. alterniflora community was re-established. Thus, after eradication of S. alterniflora, control measures should be maintained to prevent the re-establishment of S. alterniflora. The results of this demonstration project indicate a potentially useful and effective approach for the control and management of large-scale invasion by S. alterniflora on saltmarshes in the Yangtze Estuary, China. 相似文献
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基于高光谱的射阳河口悬浮泥沙浓度定量反演研究 总被引：1，自引：0，他引：1
通过提取高光谱遥感信息,对射阳河口悬浮泥沙浓度与实测光谱及Hyperion影像光谱反射率进行了相关性分析,结果表明：射阳河口含沙水体对实测光谱反射率的敏感波段为898～904nm,对光谱分辨率为10nm的Hyperion影像敏感波段正好位于896nm处,以此构建的指数模型,其相关指数达到0．89。模型的检验显示,相对根均方差值为38．78％,表明单波段896nm对预测射阳河口的悬沙质量浓度具有良好的精度。由于试验取样时间与Hyperion影像的成像时间相匹配,此时水流场较稳定,河口水体中的泥沙运移与扩散规律与影像解译结果相似,即：近岸悬沙质量浓度高,远海浓度低;河口南侧由于属于淤长性海岸,悬沙质量浓度比北侧高。研究结果为利用高光谱分析技术构建海洋悬沙含量的定量反演模型提供了可靠依据,也为海洋水体其他物质成分的定量反演奠定了基础。 相似文献
44.
长江口泥质区18#柱样的现代沉积速率及其环境 指示意义 总被引：1，自引：0，他引：1
通过对长江口泥质区18#柱样进行137Cs和210Pb同位素测年分析,得到了柱样站点的现代沉积速率。结果表明,近50多年来沉积速率较大,且呈现阶段性差异：由137Cs时标计年法得到柱样1954—1964年的沉积速率为5.9 cm/yr,1964—2006年减小为 3.36 cm/yr;沉积柱样的210Pb剖面呈两段分布,由此得到沉积速率120～225 cm为5.47 cm/yr,对应于18～100 cm减小为4.58 cm/yr。对比分析两种方法得出沉积速率开始减小的时间为1968—1972年,并且采样点区域表层可能出现侵蚀现象,为研究长江口泥质区环境演变提供了依据。 相似文献
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